Carbon monoxide methanation over Nickel promoted HZSM-5 (Ni/HZSM-5)

Authors

  • Teh Lee Peng
  • Herma Dina Setiabudi
  • Aishah Abdul Jalil

DOI:

https://doi.org/10.11113/mjcat.v4n1.143

Keywords:

CO methanation, Ni metal, HZSM-5, micro-mesoporosity, basicity

Abstract

The CO methanation was studied over 5wt% Ni loaded on HZSM-5 (5Ni/HZSM-5) catalyst via conventional impregnation technique. The catalyst’s characterization was based on X-ray diffraction (XRD), N2 physisorption, and FTIR adsorbed pyrrole analysis. Catalytic activity of CO methanation was conducted at 150-450 °C. The XRD analysis illustrated that the modification of 5wt% of Ni metal onto HZSM-5 support did not significantly altered the crystallinity compared to that of unmodified HZSM-5. The N2 physisorption result showed the co-existence of micro-mesoporosity in 5Ni/HZSM-5. The FTIR adsorbed pyrrole analysis demonstrated that 5Ni/HZSM-5 possessed high number of basic sites. The 5Ni/HZSM-5 exhibited low-temperature catalytic performance at 350 °C with 100% of CO conversion and 96.4% of CH4 yield. The CH4 yield increased to 99.6% at 450 °C with only negligible amount of CO2 was observed. The good performance in CO methanation over 5Ni/HZSM-5 can be related to the presence of Ni metal, presence of micro-mesoporosity and high basicity of the material.

References

S. Chen, A.M. Abdel-Mageed, C. Gauckler, S.E. Olesen, I. Chorkendorff, R.J. Behm, J. Catal. 373 (2019) 103.

M.V. Konishcheva, P.V. Snytnikov, V.N. Rogozhnikov, A.N. Salanov, D.I. Potemkin, V.A. Sobyanin, Catal. Commun. 118 (2019) 25.

T. Zhang, H. Ai, Q. Liu, Energy Technol. 7 (2019) 1900531.

C. Italiano, J. Llorca, L. Pino, M. Ferraro, V. Antonucci, A. Vita, Appl. Catal. B: Environ. 264 (2020) 118494.

J. Liu, C. Zheng, J. Yue, G. Xu, Chin. J. Chem. Eng. 27 (2019) 2953.

L. P. Teh, S. Triwahyono, A.A. Jalil, C.R. Mamat, S.M. Sidik, N.A.A. Fatah, R.R. Mukti, T. Shishido, RSC Adv. 5 (2015) 64651.

Y. Zang, X. Dong, D. Ping, C. Dong, CrystEngComm 19 (2017) 3156.

N. Czuma, K. Zarębska, M. Motak, M.E. Gálvez, P.D Costa, Fuel 267 (2020) 117139.

E. Kolobova, A. Pestryakov, G. Mamontov, Y. Kotolevich, N. Bogdanchikova, M. Farias, A. Vosmerikov, L. Vosmerikova, V.C. Corberan, Fuel 188 (2017) 121.

M. Thommes, K. Kaneko, A.V. Neimark, J.P. Olivier, F. Rodriguez-Reinoso, J. Rouquerol, K.S.W. Sing, Pure Appl. Chem. 87 (2015) 1051.

L. Zhang, Z. Jiang, Y. Yu, C. Sun, Y. Wang, H. Wang, RSC Adv. 5 (2015) 55825.

N. Pasupulety, A.A. Al-Zahrani, M.A. Daous, H. Driss, L.A. Petrov, Arab. J. Chem. (2020) https://doi.org/10.1016/j.arabjc.2020.02.016

B. Chen, Z. Chao, H. He, C. Huang, Y. Liu, W. Yi, X. Wei, J. An, Dalton Trans. 45 (2016) 2720.

L. Lin, X. Zhang, N. He, J. Liu, Q. Xin, H. Guo, Catalysts 9 (2019) 100.

L.P. Teh, S. Triwahyono, A.A. Jalil, M.L. Firmansyah, C.R. Mamat, Z.A. Majid, Appl. Catal. A: Gen 523 (2016) 200.

X. Guo, A. Traitangwong, M. Hu, C. Zuo, V. Meeyoo, Z. Peng, C. Li, Energ. Fuel 32 (2018) 3681.

M.C. Bacariza, M. Maleval, I. Graça, J.M. Lopes, C. Henriques, Microporous Mesoporous Mater. 274 (2019) 102.

Downloads

Published

2020-06-21

How to Cite

Lee Peng, T., Setiabudi, H. D., & Abdul Jalil, A. (2020). Carbon monoxide methanation over Nickel promoted HZSM-5 (Ni/HZSM-5). Malaysian Journal of Catalysis, 4(1). https://doi.org/10.11113/mjcat.v4n1.143

Issue

Vol. 4 No. 1 (2020): Vol 4, No 1 (2020)

Section

Research Article

License

The Malaysian Journal of Catalysis publishes open access articles under the terms of the Creative Commons Attribution (CC BY) License which permits use, distribution and reproduction in any medium, provided the original work is properly cited. 

The Department of Chemistry, Faculty of Science, UTM retains the Copyright on any research article published by Malaysian Journal of Catalysis.

Authors grant Malaysian Journal of Catalysis a license to publish the article and identify itself as the original publisher.